Electrocatalytic transformation of dialkyl malonates and arylidene- or alkylidenemalononitriles into dialkyl esters of 3-substituted 2,2-dicyanocyclopropane-1,1-dicarboxylic acids

被引：30

作者：

Elinson, MN

Feducovich, SK

Zaimovskaya, TA

Vereshchagin, AN

Gorbunov, SV

Nikishin, GI

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

[2] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2005年 / 54卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

electrolysis; electrocatalytic transformation; dialkyl malonates; arylidenemalononitriles; alkylidenemalononitriles; mediators; substituted cyclopropanes;

D O I：

10.1007/s11172-006-0008-6

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Electrolysis of alcoholic solutions of dialkyl malonates and arylidene- or alkylidenemalononitriles in the presence of NaBr in an undivided cell gave dialkyl esters of 3-substituted 2,2-dicyanocyclopropane-1,1-dicarboxylic acids in 60-90% yields.

引用

收藏

页码：1593 / 1598

页数：6

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