Role of valence-band Co 3d states on ferromagnetism in Zn1-xCoxO nanorods

被引:18
作者
Chiou, J. W.
Tsai, H. M.
Pao, C. W.
Kumar, K. P. Krishna
Chen, J. H.
Ling, D. C.
Chien, F. Z.
Pong, W. F. [1 ]
Tsai, M. -H.
Wu, J. J.
Yang, M. -H.
Liu, S. C.
Hong, I. -H.
Chen, C. -H.
Lin, H. -J.
Lee, J. F.
机构
[1] Tamkang Univ, Dept Phys, Tamsui 251, Taiwan
[2] Natl Sun Yat Sen Univ, Dept Phys, Kaohsiung 804, Taiwan
[3] Natl Cheng Kung Univ, Dept Chem Engn, Tainan 701, Taiwan
[4] Natl Synchrotron Radiat Res Ctr, Hsinchu 300, Taiwan
[5] Natl Chiayi Univ, Dept Appl Phys, Chiayi, Taiwan
关键词
D O I
10.1063/1.2432234
中图分类号
O59 [应用物理学];
学科分类号
摘要
This work investigates the electronic and ferromagnetic properties of Zn1-xCoxO nanorods using x-ray absorption, x-ray magnetic circular dichroism, and scanning photoelectron microscopy methods. The magnetic moment of Co ions in Zn1-xCoxO nanorods is found greatly reduced relative to that of the Co metal. The intensities of valence-band features near the valence-band maximum/Fermi level (E-F) of ferromagnetic nanorods are substantially larger than those of weaker ferromagnetic nanorods, suggesting that the occupation of near-E-F valence-band Co 3d states is important in determining the ferromagnetic behavior in Zn1-xCoxO nanorods. (c) 2007 American Institute of Physics.
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页数:3
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共 24 条
[1]   Comparison of the electronic structures of Zn1-xCoxO and Zn1-xMgxO nanorods using x-ray absorption and scanning photoelectron microscopies [J].
Chiou, J. W. ;
Tsai, H. M. ;
Pao, C. W. ;
Kumar, K. P. Krishna ;
Ray, S. C. ;
Chien, F. Z. ;
Pong, W. F. ;
Tsai, M. -H. ;
Chen, C. -H. ;
Lin, H. -J. ;
Wu, J. J. ;
Yang, M. -H. ;
Liu, S. C. ;
Chiang, H. H. ;
Chen, C. W. .
APPLIED PHYSICS LETTERS, 2006, 89 (04)
[2]   Diameter dependence of the electronic structure of ZnO nanorods determined by x-ray absorption spectroscopy and scanning photoelectron microscopy [J].
Chiou, JW ;
Kumar, KPK ;
Jan, JC ;
Tsai, HM ;
Bao, CW ;
Pong, WF ;
Chien, FZ ;
Tsai, MH ;
Hong, IH ;
Klauser, R ;
Lee, JF ;
Wu, JJ ;
Liu, SC .
APPLIED PHYSICS LETTERS, 2004, 85 (15) :3220-3222
[3]   Electronic structure of ZnO nanorods studied by angle-dependent x-ray absorption spectroscopy and scanning photoelectron microscopy [J].
Chiou, JW ;
Jan, JC ;
Tsai, HM ;
Bao, CW ;
Pong, WF ;
Tsai, MH ;
Hong, IH ;
Klauser, R ;
Lee, JF ;
Wu, JJ ;
Liu, SC .
APPLIED PHYSICS LETTERS, 2004, 84 (18) :3462-3464
[4]   Donor impurity band exchange in dilute ferromagnetic oxides [J].
Coey, JMD ;
Venkatesan, M ;
Fitzgerald, CB .
NATURE MATERIALS, 2005, 4 (02) :173-179
[5]   Zener model description of ferromagnetism in zinc-blende magnetic semiconductors [J].
Dietl, T ;
Ohno, H ;
Matsukura, F ;
Cibert, J ;
Ferrand, D .
SCIENCE, 2000, 287 (5455) :1019-1022
[6]   Bound magnetic polaron interactions in insulating doped diluted magnetic semiconductors [J].
Durst, AC ;
Bhatt, RN ;
Wolff, PA .
PHYSICAL REVIEW B, 2002, 65 (23) :2352051-23520510
[7]   Spin-glass-like behavior in CoO nanoparticles and the origin of exchange bias in layered CoO/Ferromagnet structures [J].
Gruyters, M .
PHYSICAL REVIEW LETTERS, 2005, 95 (07)
[8]   First-principles LDA+U calculations of the Co-doped ZnO magnetic semiconductor [J].
Hu, Shu-jun ;
Yan, Shi-shen ;
Zhao, Ming-wen ;
Mei, Liang-mo .
PHYSICAL REVIEW B, 2006, 73 (24)
[9]   Room-temperature ultraviolet nanowire nanolasers [J].
Huang, MH ;
Mao, S ;
Feick, H ;
Yan, HQ ;
Wu, YY ;
Kind, H ;
Weber, E ;
Russo, R ;
Yang, PD .
SCIENCE, 2001, 292 (5523) :1897-1899
[10]   Ferromagnetism induced by clustered Co in Co-doped anatase TiO2 thin films -: art. no. 017401 [J].
Kim, JY ;
Park, JH ;
Park, BG ;
Noh, HJ ;
Oh, SJ ;
Yang, JS ;
Kim, DH ;
Bu, SD ;
Noh, TW ;
Lin, HJ ;
Hsieh, HH ;
Chen, CT .
PHYSICAL REVIEW LETTERS, 2003, 90 (01)