Role of valence-band Co 3d states on ferromagnetism in Zn1-xCoxO nanorods

被引:18
作者
Chiou, J. W.
Tsai, H. M.
Pao, C. W.
Kumar, K. P. Krishna
Chen, J. H.
Ling, D. C.
Chien, F. Z.
Pong, W. F. [1 ]
Tsai, M. -H.
Wu, J. J.
Yang, M. -H.
Liu, S. C.
Hong, I. -H.
Chen, C. -H.
Lin, H. -J.
Lee, J. F.
机构
[1] Tamkang Univ, Dept Phys, Tamsui 251, Taiwan
[2] Natl Sun Yat Sen Univ, Dept Phys, Kaohsiung 804, Taiwan
[3] Natl Cheng Kung Univ, Dept Chem Engn, Tainan 701, Taiwan
[4] Natl Synchrotron Radiat Res Ctr, Hsinchu 300, Taiwan
[5] Natl Chiayi Univ, Dept Appl Phys, Chiayi, Taiwan
关键词
D O I
10.1063/1.2432234
中图分类号
O59 [应用物理学];
学科分类号
摘要
This work investigates the electronic and ferromagnetic properties of Zn1-xCoxO nanorods using x-ray absorption, x-ray magnetic circular dichroism, and scanning photoelectron microscopy methods. The magnetic moment of Co ions in Zn1-xCoxO nanorods is found greatly reduced relative to that of the Co metal. The intensities of valence-band features near the valence-band maximum/Fermi level (E-F) of ferromagnetic nanorods are substantially larger than those of weaker ferromagnetic nanorods, suggesting that the occupation of near-E-F valence-band Co 3d states is important in determining the ferromagnetic behavior in Zn1-xCoxO nanorods. (c) 2007 American Institute of Physics.
引用
收藏
页数:3
相关论文
共 24 条
[11]  
Kossut J., 1988, SEMICONDUCTORS SEMIM, V25
[12]   Soft-x-ray spectroscopic investigation of ferromagnetic Co-doped ZnO [J].
Krishnamurthy, S. ;
McGuinness, C. ;
Dorneles, L. S. ;
Venkatesan, M. ;
Coey, J. M. D. ;
Lunney, J. G. ;
Pattersonb, C. H. ;
Smith, K. E. ;
Learmonth, T. ;
Glans, P. -A. ;
Schmitt, T. ;
Guo, J. -H. .
JOURNAL OF APPLIED PHYSICS, 2006, 99 (08)
[13]   Study of diluted magnetic semiconductor: Co-doped ZnO [J].
Lee, HJ ;
Jeong, SY ;
Cho, CR ;
Park, CH .
APPLIED PHYSICS LETTERS, 2002, 81 (21) :4020-4022
[14]   Investigation of the phase separations and the local electronic structures of Zn1-xTxO, (T= Mn, Fe, Co) magnetic semiconductors using synchrotron radiation [J].
Lee, S. S. ;
Kim, G. ;
Wi, S. C. ;
Kang, J. -S. ;
Han, S. W. ;
Lee, Y. K. ;
An, K. -S. ;
Kwon, S. J. ;
Jung, M. H. ;
Shin, H. J. .
JOURNAL OF APPLIED PHYSICS, 2006, 99 (08)
[15]   Unusual directional dependence of exchange energies in GaAs diluted with Mn: Is the RKKY description relevant? [J].
Mahadevan, P ;
Zunger, A ;
Sarma, DD .
PHYSICAL REVIEW LETTERS, 2004, 93 (17) :177201-1
[16]   Role of the microstructure on the magnetic properties of Co-doped ZnO nanoparticles -: art. no. 103113 [J].
Martínez, B ;
Sandiumenge, F ;
Balcells, L ;
Arbiol, J ;
Sibieude, F ;
Monty, C .
APPLIED PHYSICS LETTERS, 2005, 86 (10) :1-3
[17]   Making nonmagnetic semiconductors ferromagnetic [J].
Ohno, H .
SCIENCE, 1998, 281 (5379) :951-956
[18]   X-ray absorption spectroscopy of transition-metal doped diluted magnetic semiconductors Zn1-xMxO [J].
Okabayashi, J ;
Ono, K ;
Mizuguchi, M ;
Oshima, M ;
Gupta, SS ;
Sarma, DD ;
Mizokawa, T ;
Fujimori, A ;
Yuri, M ;
Chen, CT ;
Fukumura, T ;
Kawasaki, M ;
Koinuma, H .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (07) :3573-3575
[19]   Hydrogen-mediated spin-spin interaction in ZnCoO [J].
Park, CH ;
Chadi, DJ .
PHYSICAL REVIEW LETTERS, 2005, 94 (12)
[20]   High-temperature ferromagnetism in Ni2+-doped ZnO aggregates prepared from colloidal diluted magnetic semiconductor quantum dots -: art. no. 157202 [J].
Radovanovic, PV ;
Gamelin, DR .
PHYSICAL REVIEW LETTERS, 2003, 91 (15)