Ruthenium Bis(σ-B-H) Aminoborane Complexes from Dehydrogenation of Amine-Boranes: Trapping of H2B-NH2

被引：136

作者：

Alcaraz, Gilles ^{[1
,2
]}

Vendier, Laure ^{[1
,2
]}

Clot, Eric ^{[3
]}

Sabo-Etienne, Sylviane ^{[1
,2
]}

机构：

[1] CNRS, LCC, F-31077 Toulouse, France

[2] Univ Toulouse, UPS, INPT, F-31077 Toulouse, France

[3] Univ Montpellier 2, Inst Charles Gerhardt, CNRS 5253, F-34095 Montpellier, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 05期

关键词：

aminoboranes; ammonia-borane; boron; dehydrogenation; ruthenium; CHEMICAL HYDROGEN STORAGE; BORON-NITROGEN BONDS; AMMONIA-BORANE; CATALYZED DEHYDROGENATION; SIGMA-BORANE; METAL CENTER; B BOND; ADDUCTS; LIGAND; ROUTE;

D O I：

10.1002/anie.200905970

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One small step for ammonia-borane: The simplest elementary aminoborane compound H2BNH2, which results from dehydrogenation of ammonia-borane, has been trapped by a ruthenium complex fragment leading to the isolation of a bis(σ-B-H) aminoborane complex. The analogous H 2BNHMe and H2BNMe2 complexes were also prepared. (Picture: ruthenium complex; Ru purple, P orange, N blue, B brown, H white.) © 2010 Wiley-VCH Verlag GmbH & Co. KCaA.

引用

收藏

页码：918 / 920

页数：3

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