Porous cobalt(II)-organic frameworks with corrugated walls: Structurally robust gas-sorption materials

被引：193

作者：

Humphrey, Simon M.

Chang, Jong-San

Jhung, Sung Hwa

Yoon, Ji Woong

Wood, Paul T.

机构：

[1] Korea Res Inst Chem Technol, Catalysis Ctr Mol Engn, Taejon 305600, South Korea

[2] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 1-2期

关键词：

cobalt; crystal engineering; hydrogen storage; hydrothermal synthesis; microporous materials;

D O I：

10.1002/anie.200601627

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Resilient hosts: The porous coordination solids CUK-1 (see structure; Co purple, C gray, N blue, O red/pink) and CUK-2 are synthesized from unsymmetrical ligands and CoII ions. Even after the removal of co-crystallized guests, the host frameworks are exceptionally stable. CUK-1 shows a high capacity for H2 adsorption and is one of very few materials capable of separating N2 from O2. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：272 / 275

页数：4

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