New magnetic field effects observed in micellar and fluid solutions under ultrahigh fields of up to 30 T

被引：4

作者：

Hayashi, H ^{[1
]}

Sakaguchi, Y ^{[1
]}

Wakasa, M ^{[1
]}

Mori, Y ^{[1
]}

Nishizawa, K ^{[1
]}

机构：

[1] Inst Phys & Chem Res, Mol Photochem Lab, Wako, Saitama 3510198, Japan

来源：

APPLIED MAGNETIC RESONANCE | 2000年 / 18卷 / 03期

关键词：

D O I：

10.1007/BF03162145

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

With magnetic fields of up to 30 T, we have found the saturation and reversion of magnetic field effects (MFEs) on radical pair lifetimes and escape radical yields due to the relaxation mechanism for the photoreduction of carbonyl compounds in micellar solutions as well as the saturation of MFEs on the escape radical yield due to the Delta g mechanism for the photoreduction of 4-methoxy-benzophenone with thiophenol in fluid solutions. We have also found large MFEs for several reactions involving three odd electrons in fluid solutions.

引用

页码：307 / 319

页数：13

共 13 条

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