Solution and solid state studies of some new silicon and germanium compounds stabilized by tridentate ligands

被引：18

作者：

Benin, VA ^{[1
]}

Martin, JC ^{[1
]}

Willcott, MR ^{[1
]}

机构：

[1] VANDERBILT UNIV,DEPT CHEM,NASHVILLE,TN 37235

来源：

TETRAHEDRON | 1997年 / 53卷 / 29期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4020(97)00354-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preparation and studies of novel heterocyclic compounds, containing silicon or germanium, is described. All of them incorporate the 2,6-bis(dialkylaminomethyl)-4-(1,1-dimethylethyl)phenyl tridentate ligand (Structures 1 - 2,Scheme 1) as a main substructure. The report furnishes sets of experimental data that further clarify the actual solution and solid state structures of these new molecules with potentially hypervalent silicon or germanium centers. (C) 1997 Elsevier Science Ltd.

引用

页码：10133 / 10154

页数：22

共 52 条

[1] LOW-TEMPERATURE NMR EVIDENCE SHOWS THE ELUSIVE SILICONIUM ION IS A FURTHER EXAMPLE OF TAUTOMERIC EQUILIBRIUM [J].