An unprecedented 1D ladder-like silver(I) coordination polymer with ciprofloxacin

被引：32

作者：

Chen, Zhen-Feng

Yu, Liang-Cai

Zhong, Di-Chang

Liang, Hong ^{[1
]}

Zhu, Xu-Hui

Zhou, Zhong-Yuan

机构：

[1] Guangxi Normal Univ, Sch Chem & Chem Engn, Key Lab Med Chem Resources & Mol Engn Minist Educ, Guilin 541004, Peoples R China

[2] Univ Sci & Technol China, Inst Polymer Optoelect Mat & Devices, Guangzhou 510641, Guangdong, Peoples R China

[3] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 08期

基金：

中国国家自然科学基金;

关键词：

silver; ciprofloxacin; crystal structure; coordination polymer; photoluminescence;

D O I：

10.1016/j.inoche.2006.04.034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 1D ladder-like silver(l) coordination polymer, {[Ag-4(H-CiP)(2)(CiP)(2)(NO3)(2)]center dot 4H(2)O}(n) (1) (H-Cip = ciprofloxacin, Cip = depronated ciprofloxacin) was synthesized and structurally characterized. 1 consists of pseudo-tetra-nuclear silver building blocks constructed via monodentate H-Cip and tetradentate depronated Cip ligands. In the solid state, 1 displays an emission maximum at 410 nm at room temperature. apparently originated from the intraligand excited states. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：839 / 843

页数：5

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