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Enantio-differentiating hydrogenation of prochiral ketones over modified nickel

被引：57
作者：
Osawa, T
Harada, T
Tai, A
机构：
[1] RYUKOKU UNIV,FAC SCI & TECHNOL,OTSU,SHIGA 52021,JAPAN
[2] HIMEJI INST TECHNOL,FAC SCI,KAMIGORI,HYOGO 67812,JAPAN
来源：
CATALYSIS TODAY | 1997年 / 37卷 / 04期
关键词：
alkanone; enantio-differentiation; heterogenous catalyst; hydrogenation; asymmetric modification;
D O I：
10.1016/S0920-5861(97)00027-8
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
This article reviews the enantio-differentiating hydrogenation of prochiral ketones over a asymmetrically modified catalyst, focusing on the hydrogenation of simple prochiral alkanones. The parameters affecting catalytic activity and enantio-differentiating ability are considerable in number, and each parameter should be optimized in order to attain a highperformance enantio-differentiating catalyst. Optimization of the parameters and the mode of enantio-differentiation are discussed and compared with the enantio-differentiating hydrogenation of beta-ketoesters.
引用
收藏
页码：465 / 480
页数：16
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