Stoichiometric aerobic PtII-Me bond cleavage in aqueous solutions to produce methanol and a PtII(OH) complex

被引：94

作者：

Vedernikov, AN ^{[1
]}

Binfield, SA ^{[1
]}

Zavalij, PY ^{[1
]}

Khusnutdinova, JR ^{[1
]}

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 01期

关键词：

D O I：

10.1021/ja0575171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Di(2-pyridyl)methanesulfonate ligand allows for facile aerobic oxidation of a PtIIMe complex into PtIVMe(OH)2 species and clean C-O reductive elimination of methanol from the latter in either acidic or basic aqueous solutions. Copyright © 2006 American Chemical Society.

引用

页码：82 / 83

页数：2

共 24 条

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