Metal complexes of biologically important ligands, CXIV - ferrocenyl-oxazolones as N and C donors in Pd(II), Pt(II) and Ir(III) complexes and ferrocenoyl-dipeptides, Part 113

被引：59

作者：

Bauer, W ^{[1
]}

Polborn, K ^{[1
]}

Beck, W ^{[1
]}

机构：

[1] Univ Munich, Inst Anorgan Chem, D-81377 Munich, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 579卷 / 1-2期

关键词：

2-ferrocenyl-5(4H)-oxazolones; ferrocenoyl marked dipeptides; C; N bridging oxazolone; cyclic voltammetry;

D O I：

10.1016/S0022-328X(99)00009-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2-Ferrocenyl-4R-5(4H)-oxazolones 1-5 were obtained from N-ferroclnoyl-alpha-amino acids and function as N donors in dichloro-phosphine-palladium(II) and platinum(II) complexes 6-18. The reaction of ferrocenyl-oxazolone and ferrocenyl-bis(oxazolone) with [Cp*IrCl2](2) afforded trimetallic and pentametallic complexes 19 and 20 with a C, N bridging oxazolone. Ring opening. of the ferrocenyl-oxazolones 1, 2 and 4 with alpha-amino acid esters gave N-ferrocenoyl-dipeptide esters 21-26. In the ferrocene bis(dipeptides) the two peptide esters are aligned parallel by hydrogen bonding. The structures of 6 and 19 were determined by X-ray diffraction. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：269 / 279

页数：11

共 45 条

[1] REACTIONS OF GLYCINATO COMPOUNDS OF PLATINUM(II), PALLADIUM(II), AND COPPER(II) WITH AMIDE ACETALS - SCHIFF-BASE COMPLEXES [J].

AMBACH, E ;

NAGEL, U ;

BECK, W .

CHEMISCHE BERICHTE-RECUEIL, 1983, 116 (02) :659-668

[2] A CONVENIENT PREPARATION OF DINUCLEAR PT(II) PHOSPHINE COMPLEXES [J].

BARATTA, W ;

PREGOSIN, PS .

INORGANICA CHIMICA ACTA, 1993, 209 (01) :85-87

[3]

Bauer W, 1998, EUR J INORG CHEM, P485

[4] ENANTIOSELECTIVE CATALYSIS .83. SYNTHESIS OF OPTICALLY-ACTIVE FERROCENYLALANINE [J].

BRUNNER, H ;

KONIG, W ;

NUBER, B .

TETRAHEDRON-ASYMMETRY, 1993, 4 (04) :699-707

[5] SYNTHESIS OF 1,1'-BIS(2-AMINO-2-CARBOXYETHYL)FERROCENE (1,1'-FERROCENYLBIS(ALANINE)) [J].

CARLSTROM, AS ;

FREJD, T .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (13) :4175-4180

[6] C-3 symmetric oxazolinyl ligand as catalyst in the enantioselective addition of diethylzinc to aldehydes [J].

Chan, TH ;

Zheng, GZ .

CANADIAN JOURNAL OF CHEMISTRY, 1997, 75 (06) :629-633

[7] DIRECT ELECTRICAL COMMUNICATION BETWEEN CHEMICALLY MODIFIED ENZYMES AND METAL-ELECTRODES .2. METHODS FOR BONDING ELECTRON-TRANSFER RELAYS TO GLUCOSE-OXIDASE AND D-AMINO-ACID OXIDASE [J].

DEGANI, Y ;

HELLER, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (08) :2615-2620

[8] THE FERROCENYLMETHYL(FEM) GROUP AS A HIGHLY LIPOPHILIC AND CHROMOPHORIC GROUP FOR THE MASKING OF PEPTIDE-BONDS [J].

ECKERT, H ;

SEIDEL, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (02) :159-160

[9]

Eckert H., 1986, ANGEW CHEM, V98, P168

[10] Synthesis of chiral C2-symmetric binucleating ligands [J].

Fahrni, CJ ;

Pfaltz, A .

HELVETICA CHIMICA ACTA, 1998, 81 (03) :491-506

← 1 2 3 4 5 →