The mechanism of the oxidative polymerization of aniline and the formation of supramolecular polyaniline structures

被引：489

作者：

Sapurina, Irina ^{[2
]}

Stejskal, Jaroslav ^{[1
]}

机构：

[1] Acad Sci Czech Republ, Inst Macromol Chem, CR-16206 Prague 6, Czech Republic

[2] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia

来源：

POLYMER INTERNATIONAL | 2008年 / 57卷 / 12期

关键词：

polyaniline; conducting polymer; oxidative polymerization; nanotubes; thin films; colloidal particles;

D O I：

10.1002/pi.2476

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polyaniline is one of the most important conducting and responsive polymers. A molecular mechanism for the oxidation of aniline is proposed. This mechanism explains the specific features of aniline oligomerization and polymerization in various acidity ranges. The formation of polyaniline precipitates, colloids and thin films is reviewed and discussed on the basis of the chemistry of aniline oxidation. The generation of nanostructures, i.e. granules, nanotubes, nanowires and microspheres, is also considered. Oligomers containing phenazine constitutional units play an important role in self-assembly to form templates. Polyaniline chains then grow from these templates and produce the various individual morphologies. (C) 2008 Society of Chemical Industry

引用

页码：1295 / 1325

页数：31

共 261 条

[41] INFLUENCE OF OXIDATION-STATE, PH, AND COUNTERION ON THE CONDUCTIVITY OF POLYANILINE [J].

FOCKE, WW ;

WNEK, GE ;

WEI, Y .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (22) :5813-5818

[42] THERMOCHEMISTRY AND KINETICS OF CHEMICAL POLYMERIZATION OF ANILINE DETERMINED BY SOLUTION CALORIMETRY [J].

FU, YP ;

ELSENBAUMER, RL .

CHEMISTRY OF MATERIALS, 1994, 6 (05) :671-677

[43] Ions and solvent transport across conducting polymers investigated by ac electrogravimetry. Application to polyaniline [J].

Gabrielli, C ;

Keddam, M ;

Nadi, N ;

Perrot, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2000, 485 (02) :101-113

[44] Polymerization of aniline in an aqueous system containing organic solvents [J].

Geng, YH ;

Li, J ;

Sun, ZC ;

Jing, XB ;

Wang, FS .

SYNTHETIC METALS, 1998, 96 (01) :1-6

[45] ELECTROCHEMICAL INSITU ELECTRON-PARAMAGNETIC-RES EVIDENCE OF 2 POLARON BIPOLARON STATES IN POLYANILINE [J].

GENIES, EM ;

LAPKOWSKI, M .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 236 (1-2) :199-208

[46] CYCLIC VOLTAMMETRY OF POLYANILINE - INTERPRETATION OF THE MIDDLE PEAK [J].

GENIES, EM ;

LAPKOWSKI, M ;

PENNEAU, JF .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 249 (1-2) :97-107

[47] SOLUTION CHARACTERIZATION OF SURFACTANT SOLUBILIZED POLYANILINE [J].

GETTINGER, CL ;

HEEGER, AJ ;

PINE, DJ ;

CAO, Y .

SYNTHETIC METALS, 1995, 74 (01) :81-88

[48] ON THE MECHANISM OF OXIDATIVE POLYMERIZATION OF ANILINE [J].

GOSPODINOVA, N ;

TERLEMEZYAN, L ;

MOKREVA, P ;

KOSSEV, K .

POLYMER, 1993, 34 (11) :2434-2437

[49] Conducting polymers prepared by oxidative polymerization: Polyaniline [J].

Gospodinova, N ;

Terlemezyan, L .

PROGRESS IN POLYMER SCIENCE, 1998, 23 (08) :1443-1484

[50] CHEMICAL OXIDATIVE POLYMERIZATION OF ANILINE IN AQUEOUS-MEDIUM WITHOUT ADDED ACIDS [J].

GOSPODINOVA, N ;

MOKREVA, P ;

TERLEMEZYAN, L .

POLYMER, 1993, 34 (11) :2438-2439

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