Reversible Interpenetration in a Metal-Organic Framework Triggered by Ligand Removal and Addition

被引：129

作者：

Choi, Sang Beom ^{[1
]}

Furukawa, Hiroyasu ^{[2
,3
]}

Nam, Hye Jin ^{[4
,5
]}

Jung, Duk-Young ^{[4
,5
]}

Jhon, Young Ho ^{[1
]}

Walton, Allan ^{[6
]}

Book, David ^{[6
]}

O'Keeffe, Michael ^{[7
]}

Yaghi, Omar M. ^{[2
,3
,8
]}

Kim, Jaheon ^{[1
]}

机构：

[1] Soongsil Univ, Dept Chem, Seoul 156743, South Korea

[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[3] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA

[4] Sungkyunkwan Univ, Dept Chem, Inst Basic Sci, Suwon 440746, South Korea

[5] Sungkyunkwan Univ, Sungkyunkwan Adv Inst Nanotechnol, Suwon 440746, South Korea

[6] Univ Birmingham, Sch Met & Mat, Birmingham B15 2TT, W Midlands, England

[7] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA

[8] Korea Adv Inst Sci & Technol, Ctr Global Mentoring, Grad Sch EEWS WCU, Taejon 305701, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 35期

基金：

英国工程与自然科学研究理事会;

关键词：

interpenetration; metal-organic frameworks; porosity; structural transformation; zinc; COORDINATION POLYMER; SORPTION PROPERTIES; ROOM-TEMPERATURE; CARBON-DIOXIDE; CATENATION; FUNCTIONALITY; METHANE; STORAGE; DESIGN; RINGS;

D O I：

10.1002/anie.201202925

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Caging cages: Crystals of a metal-organic framework, MOF-123 [Zn 7O 2(NBD) 5(DMF) 2] have a three-dimensional porous structure in which DMF ligands (see picture, pink) protrude into small channels. Removal of these ligands triggers the transformation of this MOF to the doubly interpenetrating form, MOF-246 [Zn 7O 2(NBD) 5]. Moreover, addition of DMF into MOF-246 triggers reverse transformation to give MOF-123. NBD=2-nitrobenzene-1,4- dicarboxylate. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8791 / 8795

页数：5

共 37 条

[1] Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database [J].

Alexandrov, E. V. ;

Blatov, V. A. ;

Kochetkov, A. V. ;

Proserpio, D. M. .

CRYSTENGCOMM, 2011, 13 (12) :3947-3958

[2] Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part II. Analysis of the Inorganic Crystal Structure Database (ICSD) [J].

Baburin, IA ;

Blatov, VA ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (08) :2452-2474

[3] Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47 [J].

Bourrelly, S ;

Llewellyn, PL ;

Serre, C ;

Millange, F ;

Loiseau, T ;

Férey, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) :13519-13521

[4]

Bureekaew S., 2010, ANGEW CHEM, V122, P7826

[5] Control of Interpenetration for Tuning Structural Flexibility Influences Sorption Properties [J].

Bureekaew, Sareeya ;

Sato, Hiroshi ;

Matsuda, Ryotaro ;

Kubota, Yoshiki ;

Hirose, Raita ;

Kim, Jungeun ;

Kato, Kenichi ;

Takata, Masaki ;

Kitagawa, Susumu .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (42) :7660-7664

[6] Heterogeneity within Order in Crystals of a Porous Metal-Organic Framework [J].

Choi, Kyung Min ;

Jeon, Hyung Joon ;

Kang, Jeung Ku ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (31) :11920-11923

[7] Solid-state structures of zinc(II) benzoate complexes. Catalyst precursors for the coupling of carbon dioxide and epoxides [J].

Darensbourg, DJ ;

Wildeson, JR ;

Yarbrough, JC .

INORGANIC CHEMISTRY, 2002, 41 (04) :973-980

[8] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[9] Microporous metal-organic framework constructed from heptanuclear zinc carboxylate secondary building units [J].

Fang, Qian-Rong ;

Zhu, Guang-Shan ;

Xue, Ming ;

Zhang, Qing-Lin ;

Sun, Jin-Yu ;

Guo, Xiao-Dan ;

Qiu, Shi-Lun ;

Xu, Shi-Tao ;

Wang, Ping ;

Wang, De-Jun ;

Wei, Yen .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (14) :3754-3758

[10] Control over Catenation in Metal-Organic Frameworks via Rational Design of the Organic Building Block [J].

Farha, Omar K. ;

Malliakas, Christos D. ;

Kanatzidis, Mercouri G. ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (03) :950-+

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