Tailoring Surface Properties of Polymeric Separators for Lithium-Ion Batteries by Cyclonic Atmospheric-Pressure Plasma

被引:29
作者
Huang, Chun [1 ]
Lin, Chi-Cheng [1 ]
Tsai, Ching-Yuan [1 ]
Juang, Ruey-Shin [1 ]
机构
[1] Yuan Ze Univ, Dept Chem Engn & Mat Sci, Chungli 32003, Taiwan
关键词
atmospheric pressure glow discharges (APGD); plasma jet; plasma treatment; polymer activation; surface modification; ELECTROCHEMICAL PERFORMANCE; POLYETHYLENE SEPARATORS; ELECTROLYTE MEMBRANE;
D O I
10.1002/ppap.201200162
中图分类号
O59 [应用物理学];
学科分类号
摘要
This paper reported surface modification and characterization of polymeric separators by cyclonic atmospheric-pressure plasma for Li-ion battery use. Water contact angles of the plasma-modified polymeric separator decreased with increasing treatment time and plasma power. Variations in surface morphology and chemical structure of the plasma-modified polymeric separators were confirmed by FESEM and XPS. XPS analysis revealed that the surfaces of plasma-modified polymeric separators had significantly higher concentrations of oxygen functional groups. Moreover, the cyclonic atmospheric-pressure plasma-modified polymeric separators showed excellent performance in electrochemical measurements.
引用
收藏
页码:407 / 415
页数:9
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