Gold (I) and (III) catalyze Suzuki cross-coupling and homocoupling, respectively

被引：115

作者：

González-Arellano, C

Corma, A

Iglesias, M

Sánchez, F

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

[2] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain

[3] CSIC, Inst Ciencia Mat, Madrid 28049, Spain

来源：

JOURNAL OF CATALYSIS | 2006年 / 238卷 / 02期

关键词：

gold catalysts for carbon-carbon bond formation; gold(I) catalysts for Suzuki cross-coupling; gold(III) catalysts for homocoupling C-C formation;

D O I：

10.1016/j.jcat.2005.12.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Trinuclear triphenylphosphine 1,2Au(I) complexes with the [N,N,0,]-tridentate unsymmetrical Schiff bases (1,2) catalyze the Suzuki cross-coupling reaction to afford nonsymmetrical biaryls in good yields, whereas the 1,2Au(111) complexes give only arylboronic homocoupling (c) 2005 Elsevier Inc. All rights reserved.

引用

页码：497 / 501

页数：5

共 46 条

[1] A collaborative effect between gold and a support induces the selective oxidation of alcohols
Abad, A
Concepción, P
Corma, A
García, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (26) : 4066 - 4069
[2] Catalysts for Suzuki-Miyaura coupling processes: Scope and studies of the effect of ligand structure
Barder, TE
Walker, SD
Martinelli, JR
Buchwald, SL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (13) : 4685 - 4696
[3] N-heterocyclic carbenes Part 26.: N-heterocyclic carbene complexes of palladium(0):: synthesis and application in the Suzuki cross-coupling reaction
Böhm, VPW
Gstöttmayr, CWK
Weskamp, T
Herrmann, WA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 595 (02) : 186 - 190
[4] SYNTHESIS OF GOLD-CONTAINING MIXED-METAL CLUSTER COMPLEXES
BRUCE, MI
NICHOLSON, BK
BINSHAWKATALY, O
SHAPLEY, JR
HENLY, T
[J]. INORGANIC SYNTHESES, 1989, 26 : 324 - 328
[5] Supported gold catalyzes the homocoupling of phenylboronic acid with high conversion and selectivity
Carrettin, S
Guzman, J
Corma, A
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (15) : 2242 - 2245
[6] Nanocrystalline CeO2 increases the activity of an for CO oxidation by two orders of magnitude
Carrettin, S
Concepción, P
Corma, A
Nieto, JML
Puntes, VF
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (19) : 2538 - 2540
[7] Lewis acids:: From conventional homogeneous to green homogeneous and heterogeneous catalysis
Corma, A
García, H
[J]. CHEMICAL REVIEWS, 2003, 103 (11) : 4307 - 4365
[8] Dyker G, 2000, ANGEW CHEM INT EDIT, V39, P4237, DOI 10.1002/1521-3773(20001201)39:23<4237::AID-ANIE4237>3.0.CO
[9] 2-A
[10] Homogeneous and heterogenized Au(III) Schiff selective and general catalysts for self-coupling base-complexes as of aryl boronic acids
González-Arellano, C
Corma, A
Iglesias, M
Sánchez, F
[J]. CHEMICAL COMMUNICATIONS, 2005, (15) : 1990 - 1992

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