Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

被引：165

作者：

Jana, Anukul ^{[1
]}

Schulzke, Carola ^{[1
]}

Roesky, Herbert W. ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 13期

关键词：

N-HETEROCYCLIC CARBENE; ALKYL AMINO CARBENES; CATALYZED DEHYDROGENATION; STABLE SILYLENE; H BOND; ACTIVATION; COMPLEX; GERMANIUM(II); DIHYDROGEN; GERMYLENE;

D O I：

10.1021/ja900880z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of L'Si [L' = CH{(C=CH2)(CMe)(2,6-iPr(2)C(6)H(3)N)(2)}] with ammonia under oxidative addition results in L'Si(H)NH2 center dot H3NBH3 functions as a source of hydrogen for the hydrogenation of N-heterocyclic carbenes and germylenes.

引用

页码：4600 / +

页数：3

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