Patterning Techniques for Metal Organic Frameworks

被引：121

作者：

Falcaro, Paolo ^{[1
]}

Buso, Dario ^{[1
,2
,4
]}

Hill, Anita J. ^{[1
,3
]}

Doherty, Cara M. ^{[1
]}

机构：

[1] CSIRO, Div Mat Sci & Engn, Clayton, Vic 3169, Australia

[2] Swinburne Univ Technol, Fac Engn & Ind Sci, Ctr Microphoton, Hawthorn, Vic 3122, Australia

[3] CSIRO, Div Proc Sci & Engn, Clayton, Vic 3169, Australia

[4] Swinburne Univ Technol, Fac Engn & Ind Sci, CUDOS, Hawthorn, Vic 3122, Australia

来源：

ADVANCED MATERIALS | 2012年 / 24卷 / 24期

基金：

澳大利亚研究理事会;

关键词：

patterning; self-assembly; MOFs; fabrication; microfluidics; SELF-ASSEMBLED MONOLAYERS; THIN-FILMS; GROWTH; FABRICATION; NUCLEATION; CHEMISTRY; CRYSTALS; SOLIDS; ROUTE; MOF-5;

D O I：

10.1002/adma.201200485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tuneable pore size and architecture, chemical properties and functionalization make metal organic frameworks (MOFs) attractive versatile stimuli-responsive materials. In this context, MOFs hold promise for industrial applications and a fervent research field is currently investigating MOF properties for device fabrication. Although the material properties have a crucial role, the ability to precisely locate the functional material is fundamental for device fabrication. In this progress report, advancements in the control of MOF positioning and precise localization of functional materials within MOF crystals are presented. Advantages and limitations of each reviewed technique are critically investigated, and several important gaps in the technological development for device fabrication are highlighted. Finally, promising patterning techniques are presented which are inspired by previous studies in organic and inorganic crystal patterning for the future of MOF lithography.

引用

页码：3153 / 3168

页数：16

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