Metal-only Lewis pairs featuring unsupported Pt→M (M = Zn or Cd) dative bonds

被引：44

作者：

Ma, Mengtao ^{[1
]}

Sidiropoulos, Anastas ^{[1
]}

Ralte, Lalrempuia ^{[1
]}

Stasch, Andreas ^{[1
]}

Jones, Cameron ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

OXIDATIVE ADDITION; BLOCK METALS; COMPLEXES; REACTIVITY; PLATINUM; HALIDES; PT-0;

D O I：

10.1039/c2cc37442k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of [Pt(PCy3)(2)] (Cy = cyclohexyl) with group 12 metal dihalides have afforded the novel metal only Lewis pair (MOLP) complexes, [(Cy3P)(2)Pt -> MX2] (M = Zn or Cd, X = Br or I), or the oxidative addition product, trans-[(Cy3P)(2)(I)PtHgI]. The zinc complex represents the first MOLP to contain an unsupported Pt -> Zn linkage.

引用

页码：48 / 50

页数：3

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