Reactivity of Pt0 complexes toward gallium(III) halides:: Synthesis of a platinum gallane complex and oxidative addition of gallium halides to Pt0

被引：75

作者：

Braunschweig, Holger ^{[1
]}

Gruss, Katrin ^{[1
]}

Radacki, Krzysztof ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 19期

关键词：

D O I：

10.1021/ic801293e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Pt(PCy3)(2)] and GaCl3 resulted in quantitative formation of the adduct [(Cy3P)(2)Pt-GaCl3], the first known platinum gallane complex. Although similar reactivity with GaBr3 and Gal(3) was expected, NMR spectroscopic data revealed a different reaction course. Crystal structure determination proved that, in the latter case, the product of the oxidative addition was formed. The resulting platinum gallyl complexes represent the first example of an oxidative addition of gallium(III) halides to low-valent transition metals.

引用

页码：8595 / 8597

页数：3

共 43 条

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