Synthesis of dendrimers with phosphine end groups at each generation

被引：9

作者：

Balueva, A ^{[1
]}

Merino, S ^{[1
]}

Caminade, AM ^{[1
]}

Majoral, JP ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 643卷

关键词：

dendrimers; phosphines; borane; Staudinger reaction;

D O I：

10.1016/S0022-328X(01)01265-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of new phenoxydiphenylphosphino derivatives allows the formation of dendrimers having phosphine end groups at each generation. The dendrimers are grown up to the fourth generation (32 phosphine terminal groups) using Staudinger reactions with azides and deprotection of borane-phosphine complexes by amines. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：112 / 124

页数：13

共 59 条

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