The potential for long-term operation of a lithium-oxygen battery using a non-carbonate-based electrolyte

被引:91
作者
Lim, Hee-Dae
Park, Kyu-Young
Gwon, Hyeokjo
Hong, Jihyun
Kim, Haegyeom
Kang, Kisuk [1 ]
机构
[1] Seoul Natl Univ, Dept Mat Sci & Engn, Seoul 151742, South Korea
基金
新加坡国家研究基金会;
关键词
CAPACITY; ETHER;
D O I
10.1039/c2cc32788k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein we demonstrate the feasibility of extended cycle operation of a Li-O-2 battery by simple control of the discharge/charge protocol. By avoiding electrolyte decomposition and the deep discharge state of the air electrode, we were able to construct a Li-O-2 cell capable of efficiently cycling over 50 times with high energy density.
引用
收藏
页码:8374 / 8376
页数:3
相关论文
共 18 条
[1]   A polymer electrolyte-based rechargeable lithium/oxygen battery [J].
Abraham, KM ;
Jiang, Z .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) :1-5
[2]   Screening for Superoxide Reactivity in Li-O2 Batteries: Effect on Li2O2/LiOH Crystallization [J].
Black, Robert ;
Oh, Si Hyoung ;
Lee, Jin-Hyon ;
Yim, Taeeun ;
Adams, Brian ;
Nazar, Linda F. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (06) :2902-2905
[3]  
Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]
[4]   α-MnO2 nanowires:: A catalyst for the O2 electrode in rechargeable lithium batteries [J].
Debart, Aurelie ;
Paterson, Allan J. ;
Bao, Jianli ;
Bruce, Peter G. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (24) :4521-4524
[5]   The Lithium-Oxygen Battery with Ether-Based Electrolytes [J].
Freunberger, Stefan A. ;
Chen, Yuhui ;
Drewett, Nicholas E. ;
Hardwick, Laurence J. ;
Barde, Fanny ;
Bruce, Peter G. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (37) :8609-8613
[6]   Reactions in the Rechargeable Lithium-O2 Battery with Alkyl Carbonate Electrolytes [J].
Freunberger, Stefan A. ;
Chen, Yuhui ;
Peng, Zhangquan ;
Griffin, John M. ;
Hardwick, Laurence J. ;
Barde, Fanny ;
Novak, Petr ;
Bruce, Peter G. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (20) :8040-8047
[7]   Lithium - Air Battery: Promise and Challenges [J].
Girishkumar, G. ;
McCloskey, B. ;
Luntz, A. C. ;
Swanson, S. ;
Wilcke, W. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (14) :2193-2203
[8]   Investigation of the O2 Electrochemistry in a Polymer Electrolyte Solid-State Cell [J].
Hassoun, Jusef ;
Croce, Fausto ;
Armand, Michel ;
Scrosati, Bruno .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (13) :2999-3002
[9]   Electrodes with high power and high capacity for rechargeable lithium batteries [J].
Kang, KS ;
Meng, YS ;
Bréger, J ;
Grey, CP ;
Ceder, G .
SCIENCE, 2006, 311 (5763) :977-980
[10]   Rechargeable Lithium/TEGDME-LiPF6/O2 Battery [J].
Laoire, Cormac O. ;
Mukerjee, Sanjeev ;
Plichta, Edward J. ;
Hendrickson, Mary A. ;
Abraham, K. M. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (03) :A302-A308