The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes

被引：77

作者：

Shindo, M

Matsumoto, K

Mori, S

Shishido, K

机构：

[1] Univ Tokushima, Inst Mat Resources, Tokushima 7708505, Japan

[2] Ibaraki Univ, Dept Environm Sci, Mito, Ibaraki 3108512, Japan

[3] Japan Sci & Technol Corp, PRESTO, Mito, Ibaraki 3108512, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 24期

关键词：

D O I：

10.1021/ja026275r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-ß-silyl-α,β-unsaturated ester, which leads to tri- and tetrasubstituted alkenes. Copyright © 2002 American Chemical Society.

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页码：6840 / 6841

页数：2

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