Effect of a remote substituent on regioselectivity in oxymercuration of unsymmetrically substituted norbornenes

被引：10

作者：

Mayo, P ^{[1
]}

Poirier, M ^{[1
]}

Rainey, J ^{[1
]}

Tam, W ^{[1
]}

机构：

[1] Univ Guelph, Dept Chem & Biochem, Guelph, ON N1G 2W1, Canada

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 44期

关键词：

oxymercuration; remote substituent effect; stereoelectronic effect; regioselectivity; norbornenes;

D O I：

10.1016/S0040-4039(99)01635-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The effect of a remote substituent on the regioselectivity in the oxymercuration of unsymmetrical substituted norbornenes has been investigated. Moderate to high levels of regioselectivity were observed with both exo- and endo-substituents at C-2 of norbornenes. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：7727 / 7730

页数：4

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