Metal-Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?

被引：1530

作者：

Farha, Omar K. ^{[1
,2
]}

Eryazici, Ibrahim ^{[1
,2
]}

Jeong, Nak Cheon ^{[1
,2
,5
]}

Hauser, Brad G. ^{[1
,2
]}

Wilmer, Christopher E. ^{[3
]}

Sarjeant, Amy A. ^{[1
,2
]}

Snurr, Randall Q. ^{[3
]}

Nguyen, SonBinh T. ^{[1
,2
]}

Yazaydin, A. Oezguer ^{[4
]}

Hupp, Joseph T. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

[3] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA

[4] Univ Surrey, Dept Chem Engn, Guildford GU2 7XH, Surrey, England

[5] Daegu Gyeongbuk Inst Sci & Technol, Dept Emerging Mat Sci, Taegu 711873, South Korea

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 36期

关键词：

HYDROGEN STORAGE; COORDINATION COPOLYMER; ENERGY-TRANSFER; ADSORPTION; DESIGN; ACTIVATION; POROSITY; ROUTE;

D O I：

10.1021/ja3055639

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have synthesized, characterized, and computationally simulated/validated the behavior of two new metal organic framework (MOF) materials displaying the highest experimental Brunauer-Emmett-Teller (BET) surface areas of any porous materials reported to date (similar to 7000 m(2)/g). Key to evacuating the initially solvent-filled materials without pore collapse, and thereby accessing the ultrahigh areas, is the use of a supercritical CO2 activation technique. Additionally, we demonstrate computationally that by shifting from phenyl groups to "space efficient" acetylene moieties as linker expansion units, the hypothetical maximum surface area for a MOF material is substantially greater than previously envisioned (similar to 14600 m(2)/g (or greater) versus similar to 10500 m(2)/g).

引用

页码：15016 / 15021

页数：6

共 54 条

[21] Independent verification of the saturation hydrogen uptake in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal-organic frameworks [J].

Furukawa, Hiroyasu ;

Miller, Michael A. ;

Yaghi, Omar M. .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) :3197-3204

[22] Ultrahigh Porosity in Metal-Organic Frameworks [J].

Furukawa, Hiroyasu ;

Ko, Nakeun ;

Go, Yong Bok ;

Aratani, Naoki ;

Choi, Sang Beom ;

Choi, Eunwoo ;

Yazaydin, A. Oezguer ;

Snurr, Randall Q. ;

O'Keeffe, Michael ;

Kim, Jaheon ;

Yaghi, Omar M. .

SCIENCE, 2010, 329 (5990) :424-428

[23] A non-interpenetrated porous metal-organic framework with high gas-uptake capacity [J].

Han, Dong ;

Jiang, Fei-Long ;

Wu, Ming-Yan ;

Chen, Lian ;

Chen, Qi-Hui ;

Hong, Mao-Chun .

CHEMICAL COMMUNICATIONS, 2011, 47 (35) :9861-9863

[24] Metal-organic frameworks as efficient materials for drug delivery [J].

Horcajada, Patricia ;

Serre, Christian ;

Vallet-Regi, Maria ;

Sebban, Muriel ;

Taulelle, Francis ;

Ferey, Gerard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (36) :5974-5978

[25]

Horike S, 2009, NAT CHEM, V1, P695, DOI [10.1038/nchem.444, 10.1038/NCHEM.444]

[26] Hydrogen Storage in Metal-Organic Frameworks [J].

Hu, Yun Hang ;

Zhang, Lei .

ADVANCED MATERIALS, 2010, 22 (20) :E117-E130

[27] Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5) [J].

Kaye, Steven S. ;

Dailly, Anne ;

Yaghi, Omar M. ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (46) :14176-+

[28] Energy Transfer Dynamics in Metal-Organic Frameworks [J].

Kent, Caleb A. ;

Mehl, Brian P. ;

Ma, Liqing ;

Papanikolas, John M. ;

Meyer, Thomas J. ;

Lin, Wenbin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (37) :12767-12769

[29] Route to a Family of Robust, Non-interpenetrated Metal-Organic Frameworks with pto-like Topology [J].

Klein, Nicole ;

Senkovska, Irena ;

Baburin, Igor A. ;

Gruenker, Ronny ;

Stoeck, Ulrich ;

Schlichtenmayer, Maurice ;

Streppel, Barbara ;

Mueller, Uwe ;

Leoni, Stefano ;

Hirscher, Michael ;

Kaskel, Stefan .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (46) :13007-13016

[30] A crystalline mesoporous coordination copolymer with high microporosity [J].

Koh, Kyoungmoo ;

Wong-Foy, Antek G. ;

Matzger, Adam J. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (04) :677-680

← 1 2 3 4 5 6 →