Synthetic ventures inspired by biosynthetic hypotheses: the evolution of a method for the oxidative amidation of phenols

被引：58

作者：

Ciufolini, Marco A.

Canesi, Sylvain

Ousmer, Malika

Braun, Norbert A.

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

[2] Univ Lyon 1, CNRS, UM 5181, Lab Synth & Methodol Organ, F-69622 Villeurbanne, France

[3] Ecole Super Chim Phys Elect Lyon, F-69622 Villeurbanne, France

来源：

TETRAHEDRON | 2006年 / 62卷 / 22期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/j.tet.2006.01.111

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We describe the development of a technique for the oxidative conversion of 4-alkyl phenols to derivatives of the corresponding 4-alkyl-4-amino-2,5-cyclohexanediones. This transformation, which was inspired by biogenetic considerations, constitutes a key step in the total syntheses of FR-901483, TAN-1251C, and cylindricine C. (c) 2006 Elsevier Ltd. All rights reserved.

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页码：5318 / 5337

页数：20

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