Efficient mechanochemical synthesis of tris(pyrazolylborate) complexes of manganese(II), cobalt(II) and nickel(II)

被引：27

作者：

Kolotilov, SV

Addison, AW

Trofimenko, S

Dougherty, W

Pavlishchuk, VV

机构：

[1] Natl Acad Sci Ukraine, Lab Spectroscopy, LV Pisarzhevskii Inst Phys Chem, UA-03028 Kiev, Ukraine

[2] Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA

[3] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 04期

关键词：

mechanochemistry; tris(pyrazolylborate); 3d-metals; X-ray structure; electronic spectra;

D O I：

10.1016/j.inoche.2004.01.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mechanochemical synthesis of Mn(II), Co(II) and Ni(II) tris(pyrazolylborates) (Tp(-)) was developed, which enabled preparation of metal complexes of the type TpMCl and TpMCl.Hpz type (Hpz is the substituted pyrazole generated by hydrolysis of the correspondin g Tp(-) ligand). The X-ray structure of a new Co(II) tris(pyrazolylborate) and the electronic spectra of these coordination compounds are discussed. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：485 / 488

页数：4

共 27 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].