The association of water in ionic liquids:: A reliable measure of polarity

被引：268

作者：

Koeddermann, Thorsten ^{[1
]}

Wertz, Christiane ^{[1
]}

Heintz, Andreas ^{[1
]}

Ludwig, Ralf ^{[1
]}

机构：

[1] Univ Rostock, Inst Chem, Phys Chem Abt, D-18051 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 22期

关键词：

density functional calculations; ionic liquids; IR spectroscopy; polarity; water;

D O I：

10.1002/anie.200504471

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water molecules can be used as a sensitive probe for measuring the polarity of ionic liquids (ILs). A combination of FTIR spectroscopy and DFT calculations was used to determine the molecular state of water in ILs. The picture shows a possible configuration of H2O in 1-ethyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)-imide (red O, white H, blue N, black C, yellow S, shaded yellow F). (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3697 / 3702

页数：6

共 48 条

[21] Thermodynamic properties of mixtures containing ionic liquids.: 4.: LLE of binary mixtures of [C2MIM][NTf2] with propan-1-ol, butan-1-ol, and pentan-1-ol and [C4MIM][NTf2] with cyclohexanol and 1,2-hexanediol including studies of the influence of small amounts of water [J].

Heintz, A ;

Lehmann, JK ;

Wertz, C ;

Jacquemin, J .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (03) :956-960

[22] Thermodynamic properties of mixtures containing ionic liquids. 3. Liquid-liquid equilibria of binary mixtures of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide with propan-1-ol, butan-1-ol, and pentan-1-ol [J].

Heintz, A ;

Lehmann, JK ;

Wertz, C .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2003, 48 (03) :472-474

[23] Room temperature ionic liquids as novel media for 'clean' liquid-liquid extraction [J].

Huddleston, JG ;

Willauer, HD ;

Swatloski, RP ;

Visser, AE ;

Rogers, RD .

CHEMICAL COMMUNICATIONS, 1998, (16) :1765-1766

[24] Dynamics of solvation of the fluorescent state of some electron donor-acceptor molecules in room temperature ionic liquids, [BMIM][(CF3SO2)2N] and [EMIM][(CF3SO2)2N] [J].

Karmakar, R ;

Samanta, A .

JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (38) :7340-7346

[25] Steady-state and time-resolved fluorescence behavior of C153 and PRODAN in room-temperature ionic liquids [J].

Karmakar, R ;

Samanta, A .

JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (28) :6670-6675

[26]

Kazarian SG, 2001, AM LAB, V33, P44

[27] Formation of water clusters in a hydrophobic solvent [J].

Köddermann, T ;

Schulte, F ;

Huelsekopf, M ;

Ludwig, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (40) :4904-4908

[28]

KODDERMANN T, 2003, ANGEW CHEM, V115, P5052

[29]

Ludwig R, 2001, ANGEW CHEM INT EDIT, V40, P1808, DOI 10.1002/1521-3773(20010518)40:10<1808::AID-ANIE1808>3.3.CO

[30]

2-T

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