Structural chemistry of vanadium oxides with open frameworks

被引:326
作者
Zavalij, PY [1 ]
Whittingham, MS
机构
[1] SUNY Binghamton, Mat Res Ctr, Binghamton, NY 13902 USA
[2] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE | 1999年 / 55卷
关键词
D O I
10.1107/S0108768199004000
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The present work is dedicated to a crystal-chemical and topographical analysis of vanadium oxides with open structures. The review covers, apart from a few exceptions, only pure vanadium oxide structures with vanadium in oxidation states greater than +3. Purely tetrahedral frameworks are not discussed because of their traditional, well known crystal chemistry and only a few examples of cluster compounds are provided. Structural classification and notation of vanadium oxide frameworks are proposed based on the following scheme: polyhedra --> chain --> layer --> three-dimensional framework. Thus, approximately 60 types of vanadium oxide frameworks are divided into five classes by type of coordination polyhedra present and into 14 subclasses by a more complex structural formation. Details are also given of the analysis of vanadium-oxygen coordination polyhedra and their metamorphosis: tetrahedron-trigonal bipyramid-square pyramid-octahedron, as well as the combinatorial deduction of possible structures for the most common framework types.
引用
收藏
页码:627 / 663
页数:37
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