Indium as a radical initiator in aqueous media: intermolecular alkyl radical addition to C=N and C=C bond

被引：52

作者：

Miyabe, H

Ueda, M

Nishimura, A

Naito, T

机构：

[1] Kobe Pharmaceut Univ, Kobe, Hyogo 6588558, Japan

[2] Kyoto Univ, Grad Sch Pharmaceut Sci, Sakyo Ku, Kyoto 6068501, Japan

来源：

TETRAHEDRON | 2004年 / 60卷 / 19期

基金：

日本学术振兴会;

关键词：

indium; radical; water; imine; oxime ether; hydrazone;

D O I：

10.1016/j.tet.2004.03.040

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The carbon-carbon bond-forming method in aqueous media was investigated by using indium as a single-electron transfer radical initiator. The indium-mediated intermolecular alkyl radical addition to imine derivatives and electron-deficient C=C bond proceeded effectively. (C) 2004 Elsevier Ltd. All rights reserved.

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收藏

页码：4227 / 4235

页数：9

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