Totally atom economical tandem-metathesis and Diels-Alder approach to polycyclic compounds

被引:50
作者
Banti, D [1 ]
North, M [1 ]
机构
[1] Kings Coll London, Dept Chem, London WC2R 2LS, England
关键词
D O I
10.1016/S0040-4039(02)00009-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Norbornene derivatives bearing pendant alkynes undergo a series of tandem metathesis reaction when treated with Grubbs' catalyst. The products of this cascade are dienes which can be trapped in situ by dienophiles in Diels-Alder reactions to yield polycyclic compounds. (C) 2002 Elsevier Science Ltd. All rights reserved.
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收藏
页码:1561 / 1564
页数:4
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