A One-Pot, Single-Solvent Process for Tandem, Catalyzed C-H Borylation-Suzuki-Miyaura Cross-Coupling Sequences

被引:49
作者
Harrisson, Peter [1 ]
Morris, James [2 ]
Steel, Patrick G. [1 ]
Marder, Todd B. [1 ]
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Jealotts Hill Int Res Ctr, Syngenta Ltd, Bracknell RG42 6EY, Berks, England
基金
英国工程与自然科学研究理事会;
关键词
biaryls; cross-coupling; homogeneous catalysis; boronate ester; tandem reactions; 1,3-DISUBSTITUTED ARENES; COMPLEXES; PINACOLBORANE; ROUTE;
D O I
10.1055/s-0028-1087374
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Methyl tert-butyl ether is a Suitable solvent for iridium-catalyzed C-H borylation followed, in the same pot, by palladium-catalyzed Suzuki-Miyaura cross-coupling sequences, giving high yields of biaryls.
引用
收藏
页码:147 / 150
页数:4
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