A One-Pot, Single-Solvent Process for Tandem, Catalyzed C-H Borylation-Suzuki-Miyaura Cross-Coupling Sequences

被引：49

作者：

Harrisson, Peter ^{[1
]}

Morris, James ^{[2
]}

Steel, Patrick G. ^{[1
]}

Marder, Todd B. ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Jealotts Hill Int Res Ctr, Syngenta Ltd, Bracknell RG42 6EY, Berks, England

来源：

SYNLETT | 2009年 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

biaryls; cross-coupling; homogeneous catalysis; boronate ester; tandem reactions; 1,3-DISUBSTITUTED ARENES; COMPLEXES; PINACOLBORANE; ROUTE;

D O I：

10.1055/s-0028-1087374

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methyl tert-butyl ether is a Suitable solvent for iridium-catalyzed C-H borylation followed, in the same pot, by palladium-catalyzed Suzuki-Miyaura cross-coupling sequences, giving high yields of biaryls.

引用

页码：147 / 150

页数：4

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