Heterogeneous basic catalysts for the transesterification and the polycondensation reactions in PET production from DMT

被引：43

作者：

Di Serio, M ^{[1
]}

Tesser, R ^{[1
]}

Ferrara, A ^{[1
]}

Santacesaria, E ^{[1
]}

机构：

[1] Univ Naples Federico II, Dipartimento Chim, I-80126 Naples, Italy

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 212卷 / 1-2期

关键词：

transesterification; polycondensation; dimethyl terephthalate; poly(ethylene terephthalate); heterogeneous catalysts;

D O I：

10.1016/j.molcata.2003.10.032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

The use of heterogeneous basic catalysts in both dimethyl terephthalate (DMT) transesterification with ethylene glycol (EG) and successive polycondensation of the obtained prepolymer, was investigated. To this end, Al2O3, calcined Al-Mg hydrotalcite with different Al/(Al + Mg) theoretical atomic ratios, and MgO were tested in transesterification and polycondensation reactions and characterised. It was shown that both the calcined Al-Mg hydrotalcites and magnesium oxides are active in the DMT transesterification reaction with EG and in the successive prepolymer polycondensation. The observed activities were compared to the results of characterisations of catalysts. Moreover, the obtained PETs have chemical and physical properties very close to those of commercial samples. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：251 / 257

页数：7

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