Environmental assessment of single-walled carbon nanotube processes

被引:111
作者
Healy, Meagan L. [1 ]
Dahlben, Lindsay J. [1 ]
Isaacs, Jacqueline A. [1 ,2 ]
机构
[1] Northeastern Univ, Dept Mech & Ind Engn, Boston, MA 02115 USA
[2] Northeastern Univ, Ctr High Rate Nanomfg, Boston, MA 02115 USA
基金
美国国家科学基金会;
关键词
environmental impact; industrial ecology; life cycle assessment (LCA); manufacturing; nanomaterials; nanotechnology;
D O I
10.1111/j.1530-9290.2008.00058.x
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The environmental assessment of nanomanufacturing during the initial process design phase should lead to the development of competitive, safe, and environmentally responsible engineering and commercialization. Given the potential benefits and concerns regarding the use of single-walled carbon nanotubes (SWNTs), three SWNT production processes have been investigated to assess their associated environmental impacts. These processes include arc ablation (arc), chemical vapor deposition (CVD), and high-pressure carbon monoxide (HiPco). Without consideration of the currently unknown impacts of SWNT dispersion or other health impacts, life cycle assessment (LCA) methodology is used to analyze the environmental impact and provide a baseline for the environmental footprint of each manufacturing process. Although the technical attributes of the product resulting from each process may not be fully comparable, this study presents comparisons that show that the life cycle impacts are dominated by energy, specifically the electricity used in production. Under base case yield conditions, HiPco shows the lowest environmental impact, while the arc process has the lowest impact under best case yield conditions.
引用
收藏
页码:376 / 393
页数:18
相关论文
共 70 条
[11]   Gas-phase production of carbon single-walled nanotubes from carbon monoxide via the HiPco process: A parametric study [J].
Bronikowski, MJ ;
Willis, PA ;
Colbert, DT ;
Smith, KA ;
Smalley, RE .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2001, 19 (04) :1800-1805
[12]  
CHAI C, 2005, CARBON NONOTUBES DEF
[13]   The potential environmental impact of engineered nanomaterials [J].
Colvin, VL .
NATURE BIOTECHNOLOGY, 2003, 21 (10) :1166-1170
[14]  
*DOE, 2007, APPR NAN ESH
[15]   Carbon nanotubes: A review of their properties in relation to pulmonary toxicology and workplace safety [J].
Donaldson, Ken ;
Aitken, Robert ;
Tran, Lang ;
Stone, Vicki ;
Duffin, Rodger ;
Forrest, Gavin ;
Alexander, Andrew .
TOXICOLOGICAL SCIENCES, 2006, 92 (01) :5-22
[16]   The Nanomanufacturing programme at the National Science Foundation [J].
Doumanidis, H .
NANOTECHNOLOGY, 2002, 13 (03) :248-252
[17]   Health and environmental impact of nanotechnology: Toxicological assessment of manufactured nanoparticles [J].
Dreher, KL .
TOXICOLOGICAL SCIENCES, 2004, 77 (01) :3-5
[18]  
ELLENBECKER M, 2008, J SCI TECHNOLOGY ADV
[19]  
*EPA, 2007, FIN NAN WHIT PAP
[20]   Effects of fullerenes and single-wall carbon nanotubes on murine and human macrophages [J].
Fiorito, S ;
Serafino, A ;
Andreola, F ;
Bernier, P .
CARBON, 2006, 44 (06) :1100-1105