A Luminescent Metal-Organic Framework with Lewis Basic Pyridyl Sites for the Sensing of Metal Ions

被引：1139

作者：

Chen, Banglin ^{[1
,2
]}

Wang, Liangbo ^{[1
]}

Xiao, Yunqing ^{[1
]}

Fronczek, Frank R. ^{[3
]}

Xue, Ming ^{[2
]}

Cui, Yuanjing ^{[1
]}

Qian, Guodong ^{[1
]}

机构：

[1] Zhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China

[2] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78539 USA

[3] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 03期

基金：

中国国家自然科学基金;

关键词：

cations; europium; luminescence; metal-organic frameworks; sensors; MICROPOROUS METAL; COORDINATION POLYMERS; HYDROGEN STORAGE; SORPTION; RELEASE; LIGAND; ADSORPTION; DESIGN; FUNCTIONALIZATION; CONNECTIVITY;

D O I：

10.1002/anie.200805101

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It all makes sense: A rationally developed europium metal-organic framework incorporating immobilized Lewis basic pyridyl sites oriented towards the center of one-dimensional channels is a rare example of a luminescent porous MOF. By comparison of the luminescence intensity quenching effects of various incorporated Lewis acidic metal cations, the MOF exhibits sensor capability. (Graph Presented) © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：500 / 503

页数：4

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