Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter

被引：295

作者：

Park, Young Kwan ^{[1
]}

Choi, Sang Beom

Kim, Hyunuk

Kim, Kimoon

Won, Byoung-Ho

Choi, Kihang

Choi, Jung-Sik

Ahn, Wha-Seung

Won, Nayoun

Kim, Sungjee

Jung, Dong Hyun

Choi, Seung-Hoon

Kim, Ghyung-Hwa

Cha, Sun-Shin

Jhon, Young Ho

Yang, Jin Kuk

Kim, Jaheon

机构：

[1] Soongsil Univ, Dept Chem, Seoul 156743, South Korea

[2] Pohang Univ Sci & Technol, Natl Creative Res Ctr Smart Supramol, Dept Chem, Pohang 790784, South Korea

[3] Korea Univ, Dept Chem, Seoul 136704, South Korea

[4] Inha Univ, Dept Chem Engn, Inchon 420751, South Korea

[5] Pohang Univ Sci & Technol, Dept Chem, Pohang 790784, South Korea

[6] Insilicotech Co Ltd, Songnam 463805, South Korea

[7] Pohang Accelerator Lab, Beamline Div, Pohang 790784, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 43期

关键词：

adsorption; luminescence; mesoporous materials; metal-organic frameworks; terbium;

D O I：

10.1002/anie.200702324

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Supersized pores: A new mesoporous metal-organic framework that is mainly composed of Tb3+ ions and tripodal carboxylate ligands has cages of 3.9 and 4.7 nm in diameter (see picture). The evacuated framework is robust and can accommodate gases or ferrocene molecules, as verified by gas-sorption measurements and luminescence studies. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8230 / 8233

页数：4

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