Valence delocalization in a mixed-oxidation divanadium (IV, V) complex electrogenerated from its structurally characterized divanadium (V) analogue with a tridentate (ONO) ligand

被引：145

作者：

Dinda, R

Sengupta, P

Ghosh, S ^{[1
]}

Mak, TCW

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, W Bengal, India

[2] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 06期

关键词：

D O I：

10.1021/ic010865t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new complex containing the {OVv(mu-O)(VO)-O-v}(4+) unit has been synthesized and structurally characterized. Cyclic voltammogram of this complex showed that the two V-V centers of the V2O34+ core are found to undergo electrochemical reduction in two distinctly separate steps not observed previously in similar systems. A rare mixed-oxidation state species [L(O)(VOV)-O-IV(O)L](-) has been electrogenerated from the structurally characterized parent divanadium (V) species in solution state and characterized by IR, EPR, and electronic spectroscopy.

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页码：1684 / +

页数：6

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