Synthesis and reactivity of cobalt boryl complexes

被引：72

作者：

Adams, CJ

Baber, RA

Batsanov, AS

Bramham, G

Charmant, JPH

Haddow, MF

Howard, JAK

Lam, WH

Lin, ZY

Marder, TB ^{[1
]}

Norman, NC

Orpen, AG

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England

[3] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

DALTON TRANSACTIONS | 2006年 / 11期

关键词：

D O I：

10.1039/b516594f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between [Co(PMe3)(4)] and B-2,(4-Mecat)(2) (4-Mecat = 1,2-O-2-4-MeC6H3) or between [Co(PMe2Ph)(4)] and B-2(cat)(2) (cat = 1,2-O2C6H4) affords the paramagnetic Co(II) bisboryl complexes [Co(PMe3)(3){B(4-Mecat)}(2)] and [Co(PMe2Ph)(3) {B(cat)}(2)] respectively, both of which have been structurally characterised. ESR data and preliminary diboration and boryl transfer reactivity studies are also presented. The reaction between [CoMe(PMe3)(4)] and B-2(cat)(2) affords the Co(I) monoboryl complex [Co(PMe3)(4){B(cat)}].

引用

页码：1370 / 1373

页数：4

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