Conformational restriction by intramolecular hydrogen bonding. Carbohydrate-carbohydrate self-assembly.

被引：14

作者：

delaPaz, ML

Ellis, G

Penades, S

Vicent, C

机构：

[1] CSIC,INST QUIM ORGAN,DEPT QUIM ORGAN BIOL,GRP CARBOHIDRATOS,E-28006 MADRID,SPAIN

[2] CSIC,INST CIENCIA & TECNOL POLIMEROS,DEPT FIS & INGN,E-28006 MADRID,SPAIN

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(97)00156-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

NMR data (chemical shifts, NOEs, coupling constants and variable temperature experiments), FT-IR data and MM2(.) molecular mechanics calculations have allowed us to demonstrate that 3-amido-1,6-anhydro-3-deoxy-beta-D-glucopyranose acts as a hydroxyl-based interaction unit and provides conformational control of self-recognition processes by intramolecular hydrogen bonding. (C) 1997 Elsevier Science Ltd.

引用

收藏

页码：1659 / 1662

页数：4

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