BaTiO3/TiO2 heterostructure nanotube arrays for improved photoelectrochemical and photocatalytic activity

被引:84
作者
Li, Rui [1 ]
Li, Qiuye [1 ]
Zong, Lanlan [1 ]
Wang, Xiaodong [1 ]
Yang, Jianjun [1 ]
机构
[1] Henan Univ, Key Lab Special Funct Mat, Kaifeng 475004, Peoples R China
基金
中国国家自然科学基金;
关键词
TiO2 nanotube array; BaTiO3/TiO2; heterojuction; Photoelectrochemistry; Photocatalysis; BICOMPONENT WO3/TIO2 FILMS; PHOTOCHEMICAL REACTIVITY; TITANIA NANOTUBES; WO3; ELECTRODES; TIO2; DEGRADATION; FABRICATION; OXIDATION; DYES;
D O I
10.1016/j.electacta.2012.12.073
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
BaTiO3/TiO2 heterostructure nanotube arrays were fabricated by in situ hydrothermal method using TiO2 nanotubes as both template and reactant. The BaTiO3/TiO2 heterostructures were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques. Compared with pure TiO2 nanotube arrays, the BaTiO3/TiO2 heterostructures exhibited enhanced photocurrent under UV light irradiation. The electrochemical impedance spectra (EIS) showed that the impedance arc radius of BaTiO3/TiO2 heterostructures was much smaller, indicating an improved charge carrier separation ability was achieved. In addition, the BaTiO3/TiO2 heterostructure nanotube arrays displayed a higher photocatalytic activity for methylene blue degradation. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:30 / 35
页数:6
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