In situ synthesis of magnetically recyclable graphene-supported Pd@Co core-shell nanoparticles as efficient catalysts for hydrolytic dehydrogenation of ammonia borane

被引：142

作者：

Wang, Jun ^{[1
,2
]}

Qin, Yu-Ling ^{[1
]}

Liu, Xiang ^{[2
]}

Zhang, Xin-Bo ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

[2] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2012年 / 22卷 / 25期

基金：

中国国家自然科学基金;

关键词：

CHEMICAL HYDROGEN STORAGE; GENERATION; OXIDATION; OXIDE;

D O I：

10.1039/c2jm32229c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Graphene supported Pd@Co core-shell nanocatalysts with magnetically recyclability were synthesized via the in situ synthesis strategy utilizing the distinction in reduction potentials of the two precursors with appropriate reductant. The as-synthesized catalysts exerted satisfied catalytic activity (916 L mol(-1) min(-1)) and recycle stability for hydrolytic dehydrogenation of ammonia borane.

引用

页码：12468 / 12470

页数：3

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