The effects of zinc nitrate, zinc acetate and zinc chloride precursors on investigation of structural and optical properties of ZnO thin films

被引：180

作者：

Bacaksiz, E. ^{[1
]}

Parlak, M. ^{[2
]}

Tomakin, M. ^{[3
]}

Ozcelik, A. ^{[1
]}

Karakiz, M. ^{[4
]}

Altunbas, M. ^{[1
]}

机构：

[1] Karadeniz Tech Univ, Fac Arts & Sci, Dept Phys, TR-61080 Trabzon, Turkey

[2] Middle E Tech Univ, Dept Phys, TR-06531 Ankara, Turkey

[3] Rize Univ, Dept Phys, Rize, Turkey

[4] Kirikkale Univ, Fac Arts & Sci, Dept Phys, Kirikkale, Turkey

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2008年 / 466卷 / 1-2期

关键词：

Zinc oxide; Microrods; Spray pyrolysis; Transmittance;

D O I：

10.1016/j.jallcom.2007.11.061

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

ZnO thin films were prepared using zinc chloride, zinc acetate and zinc nitrate precursors by spray pyrolysis technique oil glass substrates at 550 degrees C. Structural and optical properties of ZnO films were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM) and optical transmittance spectra. Regardless of precursors, ZnO thin films are all in hexagonal crystallographic phase and have to (0 0 2) preferred orientation. SEM images show completely different surface morphologies for each precursor in ZnO thin films. ZnO rod was observed only for zinc chloride precursor. The optical measurements reveal that films have a low transmittance and a direct band gap approximately 3.30 eV, which is very close to band gap of intrinsic ZnO. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：447 / 450

页数：4

共 23 条

[1]

Synthesis and characterization of spray pyrolysis Zinc Oxide microrods [J].

Alver, U. ;

Kilinc, T. ;

Bacaksiz, E. ;

Kucukomeroglu, T. ;

Nezir, S. ;

Mutlu, I. H. ;

Aslan, F. .

THIN SOLID FILMS, 2007, 515 (7-8) :3448-3451

[2]

Sol-gel-derived c-axis oriented ZnO thin films [J].

Bao, DH ;

Gu, HS ;

Kuang, AX .

THIN SOLID FILMS, 1998, 312 (1-2) :37-39

[3]

Room temperature chemical vapor deposition of c-axis ZnO [J].

Barnes, TM ;

Leaf, J ;

Fry, C ;

Wolden, CA .

JOURNAL OF CRYSTAL GROWTH, 2005, 274 (3-4) :412-417

[4]

Zinc oxide single-crystal microtubes [J].

Cheng, JP ;

Guo, RY ;

Wang, QM .

APPLIED PHYSICS LETTERS, 2004, 85 (22) :5140-5142

[5]

Preparation of ZnO films by spray pyrolysis [J].

Fiddes, AJC ;

Durose, K ;

Brinkman, AW ;

Woods, J ;

Coates, PD ;

Banister, AJ .

JOURNAL OF CRYSTAL GROWTH, 1996, 159 (1-4) :210-213

[6]

Zinc oxide thin films prepared by thermal evaporation deposition and its photocatalytic activity [J].

Fouad, OA ;

Ismail, AA ;

Zaki, ZI ;

Mohamed, RM .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 62 (1-2) :144-149

[7]

Growth of ZnO submicron single-crystalline platelets, wires, and rods by ultrasonic spray pyrolysis [J].

Htay, Myo Than ;

Hashimoto, Yoshio ;

Ito, Kentaro .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2007, 46 (01) :440-448

[8]

*JOINT COMM POWD D, 1986, 361451 JCPDS ICDD

[9]

Photoelectric, stoichiometric and structural properties of n-ZnO film on p-Si [J].

Kim, HY ;

Kim, JH ;

Park, MO ;

Im, S .

THIN SOLID FILMS, 2001, 398 :93-98

[10]

Spray pyrolysis deposition of zinc oxide nanostructured layers [J].

Krunks, M. ;

Dedova, T. ;

Acik, I. Oja .

THIN SOLID FILMS, 2006, 515 (03) :1157-1160

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