A Rotaxane-Based Switchable Organocatalyst

被引：216

作者：

Blanco, Victor ^{[1
]}

Carlone, Armando ^{[1
]}

Haenni, Kevin D. ^{[1
]}

Leigh, David A. ^{[1
,2
]}

Lewandowski, Bartosz ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 21期

基金：

英国工程与自然科学研究理事会;

关键词：

Michael addition; molecular machines; molecular switches; organocatalysis; rotaxanes; MOLECULAR MACHINE; TRANSLATIONAL ISOMERISM; TRIAZOLIUM STATION; TERMINAL ALKYNES; LOGIC GATES; SHUTTLE; PROPEPTIDES; CHEMISTRY; CATALYSIS; AZIDES;

D O I：

10.1002/anie.201201364

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Switch it on! The activity of an organocatalytic group incorporated within a rotaxane architecture can be controlled by switching the position of the macrocycle. The system was used to mediate the progress of the Michael addition of an aliphatic thiol to trans-cinnamaldehyde. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5166 / 5169

页数：4

共 63 条

[31] Energy transfer switching in a bistable molecular machine [J].

Li, YJ ;

Li, H ;

Li, YL ;

Liu, HB ;

Wang, S ;

He, XR ;

Wang, N ;

Zhu, DB .

ORGANIC LETTERS, 2005, 7 (22) :4835-4838

[32] Use of anions to allow translational isomerism of a [2]rotaxane [J].

Lin, Chi-Feng ;

Lai, Chien-Chen ;

Liu, Yi-Hung ;

Peng, Shie-Ming ;

Chiu, Sheng-Hsien .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (15) :4350-4355

[33]

Lussis P, 2011, NAT NANOTECHNOL, V6, P553, DOI [10.1038/NNANO.2011.132, 10.1038/nnano.2011.132]

[34] Asymmetric multicomponent domino reactions and highly enantioselective conjugated addition of thiols to α,β-unsaturated aldehydes [J].

Marigo, M ;

Schulte, T ;

Franzén, J ;

Jorgensen, KA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (45) :15710-15711

[35]

Marlin D. S., 2006, ANGEW CHEM, V118, P83

[36] An allosterically regulated molecular shuttle. [J].

Marlin, DS ;

Cabrera, DG ;

Leigh, DA ;

Slawin, AMZ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1385-1390

[37] Complexation-induced translational isomerism: Shuttling through stepwise competitive binding [J].

Marlin, DS ;

Cabrera, DG ;

Leigh, DA ;

Slawin, AMZ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (01) :77-83

[38]

MARLIN DS, 2006, ANGEW CHEM, V118, P1413

[39]

Melchiorre P., 2008, ANGEW CHEM, V120, P6232, DOI DOI 10.1002/ANGE.200705523

[40] Asymmetric aminocatalysis - Gold rush in organic chemistry [J].

Melchiorre, Paolo ;

Marigo, Mauro ;

Carlone, Armando ;

Bartoli, Giuseppe .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (33) :6138-6171

← 1 2 3 4 5 6 7 →