Conversion of Allylic Alcohols to Stereodefined Trisubstituted Alkenes: A Complementary Process to the Claisen Rearrangement

被引：32

作者：

Belardi, Justin K. ^{[1
]}

Micalizio, Glenn C. ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 50期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1021/ja8074242

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A stereoselective method for the conversion of allylic alcohols to (Z)-trisubstituted alkenes is presented. Overall, the reaction sequence described is stereochemically complementary to related Claisen rearrangement reactions processes that typically deliver the stereoisomeric trisubstituted alkene containing products.

引用

收藏

页码：16870 / +

页数：4

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