Guest-induced asymmetry in a metal-organic porous solid with reversible single-crystal-to-single-crystal structural transformation

被引：303

作者：

Maji, TK

Mostafa, G

Matsuda, R

Kitagawa, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Katsura, Kyoto 6158510, Japan

[2] Jadavpur Univ, Dept Phys, Kolkata 700032, W Bengal, India

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 49期

关键词：

D O I：

10.1021/ja0561439

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metal-organic honeycomb-like 2D pillared-bilayer open framework has been constructed which shows dynamic sponge-like single-crystal-to-single-crystal transformation upon dehydration and rehydration. The dehydrated acentric nonporous phase transformed to the porous centric phase with the selective adsorbate concomitant with the structural transformation correlated with the single-crystal structure determination. Copyright © 2005 American Chemical Society.

引用

页码：17152 / 17153

页数：2

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