Ruthenium oxide deposits prepared by cathodic electrosynthesis

被引：55

作者：

Zhitomirsky, I

GalOr, L

机构：

[1] Israel Institute of Metals, Technion-Israel Inst. of Technology, Haifa

来源：

MATERIALS LETTERS | 1997年 / 31卷 / 1-2期

关键词：

nanometer metallic ruthenium oxide; electrosynthesis; hydrolysis; electrogenerated base; deposit; thin film;

D O I：

10.1016/S0167-577X(96)00262-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Cathodic electrosynthesis of RuO2 deposits on Ni, Ti, Pt foils and Si wafers was accomplished via hydrolysis by an electrogenerated base, RuCl3 . xH(2)O, dissolved in water. By varying the current density and deposition time, the amount of the deposited material could be controlled. The deposits were characterized by XRD, TG/DTA and SEM. The crystallization behavior of the deposits was studied. Crystallite sizes were determined after annealing at different temperatures from X-ray broadening data.

引用

收藏

页码：155 / 159

页数：5

相关论文

共 31 条

[1] SYNTHESIS OF SUPERCONDUCTIVE THIN-FILMS OF YBA2CU3O7-X BY A NONAQUEOUS ELECTRODEPOSITION PROCESS [J].

ABOLMAALI, SB ;

TALBOT, JB .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (02) :443-445

[2] DEPOSITION OF CALCIUM-PHOSPHATE ON TITANIUM BY ELECTROCHEMICAL PROCESS IN SIMULATED BODY-FLUID [J].

BAN, S ;

MARUNO, S .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1993, 32 (10B) :L1577-L1580

[3] FATIGUE OF FERROELECTRIC PBZRXTIYO3 CAPACITORS WITH RU AND RUOX ELECTRODES [J].

BERNSTEIN, SD ;

WONG, TY ;

KISLER, Y ;

TUSTISON, RW .

JOURNAL OF MATERIALS RESEARCH, 1993, 8 (01) :12-13

[4] PREPARATION OF HIGH-TEMPERATURE SUPERCONDUCTOR OXIDE POWDERS BY ELECTRODEPOSITION [J].

BHATTACHARYA, RN ;

BLAUGHER, RD .

PHYSICA C, 1994, 229 (3-4) :244-250

[5] COMPARISON OF LEAD-ZIRCONATE-TITANATE THIN-FILMS ON RUTHENIUM OXIDE AND PLATINUM-ELECTRODES [J].

BURSILL, LA ;

REANEY, IM ;

VIJAY, DP ;

DESU, SB .

JOURNAL OF APPLIED PHYSICS, 1994, 75 (03) :1521-1525

[6] RUTHENIUM DIOXIDE AS CATHODE MATERIAL FOR HYDROGEN EVOLUTION IN HYDROXIDE AND CHLORATE SOLUTIONS [J].

CORNELL, A ;

SIMONSSON, D .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (11) :3123-3129

[7] ELECTROLYTIC ZRO2 COATINGS .1. ELECTROCHEMICAL ASPECTS [J].

GALOR, L ;

SILBERMAN, I ;

CHAIM, R .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (07) :1939-1942

[8] CHEMICAL VAPOR-DEPOSITION OF RUTHENIUM AND RUTHENIUM DIOXIDE FILMS [J].

GREEN, ML ;

GROSS, ME ;

PAPA, LE ;

SCHNOES, KJ ;

BRASEN, D .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (11) :2677-2685

[9] COMPOSITIONAL AND MICROSTRUCTURAL CHARACTERIZATION OF RUO2-TIO2 CATALYSTS SYNTHESIZED BY THE SOL-GEL METHOD [J].

GUGLIELMI, M ;

COLOMBO, P ;

RIGATO, V ;

BATTAGLIN, G ;

BOSCOLOBOSCOLETTO, A ;

DEBATTISTI, A .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (06) :1655-1661

[10] STUDIES ON OXIDE-COATED METAL ANODES FOR CHLOR-ALKALI CELLS [J].

HINE, F ;

YASUDA, M ;

YOSHIDA, T .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1977, 124 (04) :500-505

← 1 2 3 4 →