Synthesis of a honeycomb-like Cu-based metal-organic framework and its carbon dioxide adsorption behaviour

被引：182

作者：

Sanz, Raul ^{[1
]}

Martinez, Fernando ^{[2
]}

Orcajo, Gisela ^{[1
]}

Wojtas, Lukasz ^{[3
]}

Briones, David ^{[1
]}

机构：

[1] Rey Juan Carlos Univ, Dept Chem & Energy Technol, Mostoles 28933, Spain

[2] Rey Juan Carlos Univ, Dept Chem & Environm Technol, Mostoles 28933, Spain

[3] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 07期

关键词：

HYDROGEN ADSORPTION; COORDINATION POLYMER; SITES; STORAGE; RECOGNITION; CAPACITY; PORES;

D O I：

10.1039/c2dt32138f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein, we report on a new Cu-based MOF material, Cu-2(dhtp), structurally homologous to the honeycomb-like M-2(dhtp) series. This has been crystallized under solvothermal conditions using copper nitrate and 2,5-dihydroxyterephthalic acid as an organic linker, being the nature of the co-solvent in the synthesis media an important variable over the final physical properties of the material. The presence of isopropanol as a co-solvent leads to the formation of a pure crystalline phase with textural properties comparable to M-2(dhtp) homologues. The interesting results in CO2 adsorption properties of this new material, especially its isosteric heat of adsorption, make it a suitable MOF to be further evaluated under real conditions of industrial CO2 capture.

引用

页码：2392 / 2398

页数：7

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