Efficient synthesis of 1,5-benzodiazepines catalyzed by silica supported 12-tungstophosphoric acid

被引：47

作者：

Abdollahi-Alibeik, Mohammad ^{[1
]}

Mohammadpoor-Baltork, Iraj ^{[2
]}

Zaghaghi, Zahra ^{[1
]}

Yousefi, Behrooz H. ^{[3
]}

机构：

[1] Yazd Univ, Dept Chem, Yazd 89195741, Iran

[2] Isfahan Univ, Dept Chem, Esfahan 8174673441, Iran

[3] Tech Univ Munich, Dept Nucl Med, D-81675 Munich, Germany

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 15期

关键词：

silica supported; 12-tungstophosphoric acid; 1,5-benzodiazepine; o-phenylenediamine; heteropoly acid;

D O I：

10.1016/j.catcom.2008.07.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Silica supported 12-tungstophosphoric acid efficiently catalyzes the reaction of o-phenylenediamine with ketones under solvent free condition to afford the corresponding 1,5-benzodiazepines in good to excellent yields. The catalyst can be recovered by simple filtration and reused. (C) 2008 Elsevier B.V. All rights reserved.

引用

收藏

页码：2496 / 2502

页数：7

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