Plasma Polymer Membranes for Immobilising Metalloporphyrins

被引：20

作者：

Boscher, Nicolas D. ^{[1
]}

Duday, David ^{[1
]}

Heier, Philip ^{[2
]}

Heinze, Katja ^{[2
]}

Hilt, Florian ^{[1
]}

Choquet, Patrick ^{[1
]}

机构：

[1] Ctr Rech Publ Gabriel Lippmann, L-4422 Belvaux, Luxembourg

[2] Johannes Gutenberg Univ Mainz, Inst Inorgan & Analyt Chem, D-55128 Mainz, Germany

来源：

PLASMA PROCESSES AND POLYMERS | 2013年 / 10卷 / 04期

关键词：

composites; dielectric barrier discharges (DBD); hexamethyldisiloxane (HMDSO); immobilization of molecules; UVVis spectroscopy; DIELECTRIC BARRIER DISCHARGE; SENSITIZED SOLAR-CELLS; THIN-FILMS; SENSING CAPABILITIES; ALUMINUM FOIL; PORPHYRIN; DEPOSITION; TETRAPHENYLPORPHYRIN; CORROSION; RESPONSES;

D O I：

10.1002/ppap.201200132

中图分类号：

O59 [应用物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

Atmospheric pressure dielectric barrier discharge formation of organosilicon thin films loaded with zinc 5,10,15,20-tetraphenylporphyrin (Zn(TPP)) was investigated for different deposition conditions. UVvisible spectroscopy and scanning electron microscopy revealed the effects of the metalloporpyhrins injection parameters and the plasma polymerisation conditions can affect the dispersion of the metalloporphyrins and the morphology of the coatings. The stability of the embedded Zn(TPP) molecules was investigated by orbitrap mass spectrometry.

引用

页码：336 / 344

页数：9

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