Mild oxidative alkane functionalization with peroxides in the presence of ferrocene

被引：34

作者：

Shul'pin, Georgiy B. ^{[1
]}

Kirillova, Marina V. ^{[2
]}

Shul'pina, Lidia S. ^{[3
]}

Pombeiro, Armando J. L. ^{[2
]}

Karslyan, Eduard E. ^{[2
,3
]}

Kozlov, Yuriy N. ^{[1
]}

机构：

[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 119991, Russia

[2] Univ Tecn Lisboa, Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

[3] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

CATALYSIS COMMUNICATIONS | 2013年 / 31卷

基金：

俄罗斯基础研究基金会;

关键词：

Alkanes; Homogeneous catalysis; Hydrogen peroxide; Hydrocarboxylation; Hydroperoxidation; Iron complexes; SINGLE-POT HYDROCARBOXYLATION; HYDROGEN-PEROXIDE; AROMATIC-HYDROCARBONS; CARBOXYLIC-ACIDS; AQUEOUS SYSTEMS; IRON COMPLEXES; NONHEME IRON; H OXIDATIONS; METAL-FREE; C-H;

D O I：

10.1016/j.catcom.2012.11.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ferrocene in an unexpected emploi: alkanes can be efficiently oxygenated by H2O2 in the presence of catalytic amounts of this well-known organometallic compound in combination with pyrazine-2-carboxylic acid or 2,2'-bipyridine. Saturated hydrocarbons, RH, are also transformed into carboxylic acids, RCOOH, when reacted with the ferrocene/CO/S2O82-/H2O system in acetonitrile solution. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：32 / 36

页数：5

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