Carbonylation of amines with a tungsten(IV) carbonyl complex

被引：45

作者：

McCusker, JE ^{[1
]}

Abboud, KA ^{[1
]}

McElweeWhite, L ^{[1
]}

机构：

[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 17期

关键词：

D O I：

10.1021/om970388f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [(CO)(2)W(NPh)I-2](2) (1) with 2 equiv of piperidine yielded (CO)(2)W(NPh)I-2(pip). In the presence of excess amine, secondary amines (R2NH) were carbonylated to the formamides R2NCHO while primary amines (R'NH2) were converted to the ureas R'NH-CONHR'.

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页码：3863 / 3866

页数：4

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